Zinc and magnesium metal each reacts with hydrochloric acid to make chloride salts of the respective metals, and hydrogen gas. a 11.20-g mixture of zinc and magnesium produces 0.6854 g of hydrogen gas upon being mixed with an excess of hydrochloric acid. determine the percent magnesium by mass in the original mixture.

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14-07-2017
Chemistry

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Zinc and magnesium metal each reacts with hydrochloric acid to make chloride salts of the respective metals, and hydrogen gas. a 11.20-g mixture of zinc and magnesium produces 0.6854 g of hydrogen gas upon being mixed with an excess of hydrochloric acid. determine the percent magnesium by mass in the original mixture.

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dec77cat dec77cat · Answer 1 · 2017-07-14T17:22:57+02:00

m=11.20 g
m(H₂)=0.6854 g
M(H₂)=2.016 g/mol
M(Mg)=24.305 g/mol
M(Zn)=65.39 g/mol
w-?

m(Mg)=wm
m(Zn)=(1-w)m

Zn + 2HCl = ZnCl₂ + H₂
m₁(H₂)=M(H₂)m(Zn)/M(Zn)=M(H₂)(1-w)m/M(Zn)

Mg + 2HCl = MgCl₂ + H₂
m₂(H₂)=M(H₂)m(Mg)/M(Mg)=M(H₂)wm/M(Mg)

m(H₂)=m₁(H₂)+m₂(H₂)
m(H₂)=M(H₂)(1-w)m/M(Zn)+M(H₂)wm/M(Mg)=M(H₂)m{(1-w)/M(Zn)+w/M(Mg)}

m(H₂)=M(H₂)m{(1-w)/M(Zn)+w/M(Mg)}

(1-w)/M(Zn)+w/M(Mg)=m(H₂)/{M(H₂)m}

1/M(Zn)-w/M(Zn)+w/M(Mg)=m(H₂)/{M(H₂)m}

w(1/M(Mg)-1/M(Zn))=m(H₂)/{M(H₂)m}-1/M(Zn)

w=[m(H₂)/{M(H₂)m}-1/M(Zn)]/(1/M(Mg)-1/M(Zn))

w=0.583 (58.3%)