Which is a pair of vertical angles?
∠VRU and ∠SRT
∠TRS and ∠VRW
∠TRV and ∠WRU
∠WRV and ∠SRW

Answer: ∠TRS and ∠VRW (Choice B)
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Explanation:
Ignore ray RU. I would redraw the entire thing without ray RU as part of the picture. See below.
Notice how lines TW and SV intersect to form an X shape.
The angles TRS and VRW shown in red are opposite one another, so we consider them to be vertical angles. Vertical angles are always congruent.