21.
Explanation:
The two-digit number ab stands for 10a + b since the first digit represents 10s and the second represents units. If 10a + b = 7(a + b), then 10a + b = 7a + 7b, and so 3a = 6b, or, more simply, a = 2b. That is, the second digit must be twice the first. The smallest such number is 21.
