Respuesta :
Answer:
Composition of initial mixture is:
9.02g of NaBrO₃
15.84g of Na₂CO₃
17.06g of NaHCO₃
82.58g NaBr
Explanation:
For the reactions:
2NaBrO₃(s) ⟶ 2NaBr(s) + 3O₂(g)
2NaHCO₃(s) ⟶ Na₂O(s) + H₂O(g) + 2CO₂(g)
Na₂CO₃(s) ⟶ Na₂O(s)+CO₂(g)
All H₂O(g) comes from NaHCO₃. Thus, initial moles and mass of NaHCO₃ are:
1.83g H₂O ₓ (1 mol H₂O / 18.02g) ₓ (2 mol NaHCO₃ / 1 mol H₂O) = 0.203moles NaHCO₃ ₓ (84g / 1mol NaHCO₃) =
17.06g of NaHCO₃
CO₂ comes from NaHCO₃ and Na₂CO₃.
15.51g of CO₂ are:
15.51g CO₂ ₓ (1mol / 44.01g) = 0.352moles of CO₂
As 2 moles of NaHCO₃ produce 2 moles of CO₂, moles of CO₂ that comes from NaHCO₃ are 0.203moles NaHCO₃. Moles of CO₂ that comes from Na₂CO₃ are:
0.352mol CO₂ - 0.203mol CO₂ = 0.149mol CO₂
These moles of CO₂ are produced from:
0.149mol CO₂ ₓ (1 mol Na₂CO₃ / 1 mol CO₂) ₓ (106g / 1mol Na₂CO₃) =
15.84g of Na₂CO₃
And all O₂ comes from NaBrO₃. Initial mass of NaBrO₃ is:
2.87g O₂ ₓ (1 mol O₂ / 32g) ₓ (2 mol NaBrO₃ / 3 mol O₂) ₓ (150.9g / 1mol NaBrO₃) =
9.02g of NaBrO₃
If initial mass of the mixture was 124.5g, mass of NaBr was:
124.5g - 9.02g of NaBrO₃ - 15.84g of Na₂CO₃ - 17.06g of NaHCO₃ =
82.58g NaBr
Composition of initial mixture is:
9.02g of NaBrO₃
15.84g of Na₂CO₃
17.06g of NaHCO₃
82.58g NaBr
Composition of initial mixture is:
- 9.02g of NaBrO₃
- 15.84g of Na₂CO₃
- 17.06g of NaHCO₃
- 82.58g NaBr
For the reactions:
- 2NaBrO₃(s) ⟶ 2NaBr(s) + 3O₂(g)
- 2NaHCO₃(s) ⟶ Na₂O(s) + H₂O(g) + 2CO₂(g)
- Na₂CO₃(s) ⟶ Na₂O(s)+CO₂(g)
- H₂O(g) comes from NaHCO₃. Thus, initial moles and mass of NaHCO₃ are:
[tex]1.83g H_2O * (1 mol H_2O / 18.02g) * (2 mol NaHCO_3 / 1 mol H_2O) \\\\= 0.203moles NaHCO_3 * (84g / 1mol NaHCO_3) \\\\=17.06\text{ g of }NaHCO_3[/tex]
- CO₂ comes from NaHCO₃ and Na₂CO₃.
15.51g of CO₂ are:
[tex]15.51\text{ g } CO_2 * (1mol / 44.01g) = 0.352\text{ moles of } CO_2[/tex]
As 2 moles of NaHCO₃ produce 2 moles of CO₂, moles of CO₂ that comes from NaHCO₃ are 0.203moles NaHCO₃. Moles of CO₂ that comes from Na₂CO₃ are:
0.352mol CO₂ - 0.203mol CO₂ = 0.149mol CO₂
- These moles of CO₂ are produced from:
[tex]0.149mol CO_2 * (1 mol Na_2CO_3 / 1 mol CO_2) * (106g / 1mol Na_2CO_3) \\\\=15.84\text{ g of } Na_2CO_3[/tex]
- O₂ comes from NaBrO₃. Initial mass of NaBrO₃ is:
[tex]2.87g O_2 * (1 mol O_2 / 32g) * (2 mol NaBrO_3 / 3 mol O_2) * (150.9g / 1mol NaBrO_3) \\\\=9.02\text{ g of} NaBrO_3[/tex]
If initial mass of the mixture was 124.5g, mass of NaBr was:
124.5g - 9.02g of NaBrO₃ - 15.84g of Na₂CO₃ - 17.06g of NaHCO₃ =82.58g NaBr
Composition of initial mixture is:
- 9.02g of NaBrO₃
- 15.84g of Na₂CO₃
- 17.06g of NaHCO₃
- 82.58g NaBr
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