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Which is a Lewis acid but not a Brønsted acid? Select one: a. Fe3+ b. H3O+ c. HSO4– d. NH3 e. H2O

Respuesta :

Answer:

[tex]Fe^{3+}[/tex]

Explanation:

Brønsted acid:-

Acids are the substances which dissociate in the aqueous medium to produce electrically charged atoms ( may be molecule). Out of these species furnished, one must be a proton or the hydrogen ion, [tex]H^+[/tex].

Lewis acid:-

Compound or the ionic species that can accept electron pair from the donor compound or the ionic species.

Thus, out of the given options, [tex]NH_3[/tex] is a base, [tex]H_2O[/tex] is neutral, [tex]H_3O^+[/tex] and [tex]HSO_4^-[/tex] are Brønsted acid.

The lewis acid is :- [tex]Fe^{3+}[/tex]

Answer : The correct option is, (a) [tex]Fe^{3+}[/tex]

Explanation :

According to the Bronsted Lowry concept, Bronsted Lowry-acid is a substance that donates one or more hydrogen ion in a reaction and Bronsted Lowry-base is a substance that accepts one or more hydrogen ion in a reaction.

According to the Lewis concept, an acid is defined as a substance that accepts electron pairs and base is defined as a substance which donates electron pairs.

(a) [tex]Fe^{3+}[/tex]

It is a Lewis-acid because it can accepts electron pairs but not a Brønsted acid because it can not donates hydrogen ion.

(b) [tex]H_3O^+[/tex]

It is not a Lewis-acid because it can not accepts electron pairs but a Brønsted acid because it can donates hydrogen ion.

(c) [tex]HSO_4^-[/tex]

It is not a Lewis-acid because it can not accepts electron pairs but a Brønsted acid because it can donates hydrogen ion.

(d) [tex]NH_3[/tex]

It is not a Lewis-acid because it can not accepts electron pairs but a Brønsted acid and a base because it can donates and accept hydrogen ion.

(e) [tex]H_2O[/tex]

It is not a Lewis-acid because it can not accepts electron pairs but a Brønsted acid and a base because it can donates and accept hydrogen ion.

Hence, the [tex]Fe^{3+}[/tex] is a Lewis acid but not a Brønsted acid.