Radioactive plutonium−239 (t1/2 = 2.44 × 105 yr) is used in nuclear reactors and atomic bombs. If there are 3.50 × 102 g of the isotope in a small atomic bomb, how long will it take for the substance to decay to 1.00 × 102 g, too small an amount for an effective bomb? (Hint: Radioactive decays follow first-order kinetics.) .0000441 yr

Respuesta :

Answer:

t = 4.41 10⁻⁴ years

Explanation:

For this exercise we must use the concept of average life time, which is the time in which the quantity and substance decays in half

    [tex]T_{1/2}[/tex]  = ln2 / λ

Let's calculate the decay constant of plutonium

    λ  = ln2 /  [tex]T_{1/2}[/tex]

    λ  = ln 2 / 2.44 10⁵  

    λ  = 2.84 10⁻⁶  s⁻¹

Radioactive decay is a first order process

     N = No e (-λ   t)

Where N is the number of nuclei, the mass is this by molecular weight

    m = N PM

    m / PM = m₀ / PM e (- λ  t)

    m / m₀ = e (- λ  t)

    -λ  t = ln (m / m₀)

     t = -1 /λ   ln (m/m₀)

     t = - 1 / 2.84 10⁻⁶   ln (0.1 / 0.35)

     t = 4.41 10⁻⁴ years

The time taken for the radioactive plutonium−239 having a half-life of 2.44×10⁵ years to decay from 3.50×10² g to 1×10² g is 4.41×10⁵ years

How to determine the number of half-lives

  • Original amount (N₀) = 3.50×10²
  • Amount remaining (N) = 1×10²  g
  • Number of half-lives (n) =?

2ⁿ = N₀ / N

2ⁿ = 3.50×10² / 1×10²

2ⁿ = 3.5

Take the log of both side

Log 2ⁿ = Log 3.5

nLog 2 = Log 3.5

Divide both side by Log 2

n = Log 3.5 ÷ Log 2

n = 1.807

How to determine the time

  • Number of half-lives (n) = 1.807
  • Half-life (t½) = 2.44×10⁵ years
  • Time (t) =?

t = n × t½

t = 1.807 × 2.44×10⁵

t = 4.41×10⁵ years

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