joellianamikhai8542 joellianamikhai8542

14-09-2019
Chemistry

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In the Cannizzaro reaction of benzaldehyde ( aka solventless disproportionation of benzaldehyde in the presences of a strong base such as KOH), what is the internal reduction product?

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OrethaWilkison OrethaWilkison

22-09-2019

Answer:

Reaction products are shown below

Explanation:

In cannizaro reaction, benzaldehyde produces benzoic acid and benzyl alcohol through disproportion.
Here, a hydroxyl group first gives a nucleophilc addition at carbonyl center of benzaldehyde.
Then a hydride transfer takes place to another molecule of benzaldehyde
Thus, benzoic acid and benzyl alcohol are produced.
Full reaction mechanism has been shown below

Ver imagen OrethaWilkison

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