Dagastinium, on the other hand, is a rare material that has a temperature dependent constant pressure heat capacity of cP = 0.1 x T J/(mol.K) in the range from 273 to 303 K. What is the entropy change of 2 moles of Dagastinium between 273 and 303 K?

Respuesta :

Answer : The change in entropy is 6 J/K

Explanation :

To calculate the change in entropy we use the formula:

[tex]\Delta S=\int \frac{dQ}{T}[/tex]

and,

[tex]Q=nC_pdT[/tex]

[tex]\Delta S=n\int\limits^{T_f}_{T_i}{\frac{C_{p}dT}{T}[/tex]

where,

[tex]\Delta S[/tex] = change in entropy

n = number of moles = 2 moles

[tex]T_f[/tex] = final temperature = 303 K

[tex]T_i[/tex] = initial temperature = 273 K

[tex]C_{p}[/tex] = heat capacity at constant pressure = [tex]0.1\times T(J/K.mol)[/tex]

Now put all the given values in the above formula, we get:

[tex]\Delta S=2\int\limits^{303}_{273}{\frac{(0.1\times TdT}{T}[/tex]

[tex]\Delta S=2\times 0.1\int\limits^{303}_{273}dT[/tex]

[tex]\Delta S=2\times 0.1\times [T]^{303}_{273}[/tex]

[tex]\Delta S=2\times 0.1\times (T_f-T_i)[/tex]

[tex]\Delta S=2\times 0.1\times (303-273)[/tex]

[tex]\Delta S=6J/K[/tex]

Therefore, the change in entropy is 6 J/K