A 0.4230 g sample of impure sodium nitrate (contains sodium nitrate plus inert ingredients) was heated, converting all the sodium nitrate to 0.1080 g of sodium nitrite and oxygen gas. Determine the percent of sodium nitrate in the original sample.

Respuesta :

Answer : The percent of sodium nitrate in the original sample is, 31.35 %

Explanation : Given,

Mass of impure [tex]NaNO_3[/tex] = 0.4230 g

Mass of [tex]NaNO_2[/tex] = 0.1080 g

Molar mass of [tex]NaNO_3[/tex] = 84.99 g/mole

Molar mass of [tex]NaNO_2[/tex] = 68.99 g/mole

First we have to calculate the moles of [tex]NaNO_2[/tex].

[tex]\text{Moles of }NaNO_2=\frac{\text{Mass of }NaNO_2}{\text{Molar mass of }NaNO_2}=\frac{0.1080g}{68.99g/mole}=0.00156moles[/tex]

Now we have to calculate the moles of [tex]NaNO_3[/tex].

The balanced chemical reaction is,

[tex]NaNO_3\rightarrow NaNO_2+\frac{1}{2}O_2[/tex]

From the balanced reaction we conclude that

As, 1 mole of [tex]NaNO_2[/tex] react to give 1 mole of [tex]NaNO_3[/tex]

As, 0.00156 mole of [tex]NaNO_2[/tex] react to give 0.00156 mole of [tex]NaNO_3[/tex]

Now we have to calculate the mass of [tex]NaNO_3[/tex].

[tex]\text{Mass of }NaNO_3=\text{Moles of }NaNO_3\times \text{Molar mass of }NaNO_3[/tex]

[tex]\text{Mass of }NaNO_3=(0.00156mole)\times (84.99g/mole)=0.1326g[/tex]

Now we have to calculate the percent of sodium nitrate in the original sample.

[tex]\% \text{ of }NaNO_3=\frac{\text{Mass of }NaNO_3}{\text{Mass of impure }NaNO_3}\times 100[/tex]

[tex]\% \text{ of }NaNO_3=\frac{0.1326g}{0.4230g}\times 100=31.35\%[/tex]

Therefore, the percent of sodium nitrate in the original sample is, 31.35 %