64 is a counter example that proves Jim's conjecture as false.
Explanation
The number should be less than 100 and need to be both perfect square and perfect cubes.
[tex]64 = 8*8 = (8)^2[/tex]
So, 64 is a perfect squared number.
Now, [tex]64= 4*4*4 =(4)^3[/tex]
So, 64 is also a perfect cubed number.